An efficient microwave-assisted chelation (MWAC) post-synthetic modification method to produce hierarchical Y zeolites

Samer Abdulridha; Rongxin Zhang; Shaojun Xu; Aleksander Tedstone; Xiaoxia Ou; Jiacheng Gong; Boyang Mao; Mark Frogley; Carlo Bawn; Zhaoxia Zhou; Xinran Zhang; Sarayute Chansai; Stuart M. Holmes; Christopher Hardacre; Arthur A. Garforth; Sihai Yang; Yilai Jiao; Xiaolei Fan

doi:10.1016/j.micromeso.2020.110715

An efficient microwave-assisted chelation (MWAC) post-synthetic modification method to produce hierarchical Y zeolites

Samer Abdulridha, Rongxin Zhang, Shaojun Xu, Aleksander Tedstone, Xiaoxia Ou, Jiacheng Gong, Boyang Mao, Mark Frogley, Carlo Bawn, Zhaoxia Zhou, Xinran Zhang, Sarayute Chansai, Stuart M. Holmes, Christopher Hardacre, Arthur A. Garforth, Sihai Yang, Yilai Jiao, Xiaolei Fan

Research output: Journal Publication › Article › peer-review

19 Citations (Scopus)

Abstract

We report a low-cost, highly energy efficient microwave-assisted chelation (MWAC) method, which enabled the post-synthetic modification of synthetic zeolites for adopting hierarchical structures within minutes. Exemplified by Zeolite Y, hierarchical Y zeolites prepared in this way showed exceptional specific external surface areas of >300 m² g⁻¹ and mesopore volumes of >0.46 cm³ g⁻¹. Comparative assessments revealed that developed zeolites have shown significantly improved catalytic activities for catalysis involving large substrates, such as catalytic cracking and hydrocracking of plastics.

Original language	English
Article number	110715
Journal	Microporous and Mesoporous Materials
Volume	311
DOIs	https://doi.org/10.1016/j.micromeso.2020.110715
Publication status	Published - Feb 2021
Externally published	Yes

Keywords

Catalysis
Hierarchical zeolites
Microwave irradiation
Post-synthetic treatment

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics
Mechanics of Materials

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.micromeso.2020.110715

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Abdulridha, S., Zhang, R., Xu, S., Tedstone, A., Ou, X., Gong, J., Mao, B., Frogley, M., Bawn, C., Zhou, Z., Zhang, X., Chansai, S., Holmes, S. M., Hardacre, C., Garforth, A. A., Yang, S., Jiao, Y., & Fan, X. (2021). An efficient microwave-assisted chelation (MWAC) post-synthetic modification method to produce hierarchical Y zeolites. Microporous and Mesoporous Materials, 311, Article 110715. https://doi.org/10.1016/j.micromeso.2020.110715

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title = "An efficient microwave-assisted chelation (MWAC) post-synthetic modification method to produce hierarchical Y zeolites",

abstract = "We report a low-cost, highly energy efficient microwave-assisted chelation (MWAC) method, which enabled the post-synthetic modification of synthetic zeolites for adopting hierarchical structures within minutes. Exemplified by Zeolite Y, hierarchical Y zeolites prepared in this way showed exceptional specific external surface areas of >300 m2 g−1 and mesopore volumes of >0.46 cm3 g−1. Comparative assessments revealed that developed zeolites have shown significantly improved catalytic activities for catalysis involving large substrates, such as catalytic cracking and hydrocracking of plastics.",

keywords = "Catalysis, Hierarchical zeolites, Microwave irradiation, Post-synthetic treatment",

author = "Samer Abdulridha and Rongxin Zhang and Shaojun Xu and Aleksander Tedstone and Xiaoxia Ou and Jiacheng Gong and Boyang Mao and Mark Frogley and Carlo Bawn and Zhaoxia Zhou and Xinran Zhang and Sarayute Chansai and Holmes, {Stuart M.} and Christopher Hardacre and Garforth, {Arthur A.} and Sihai Yang and Yilai Jiao and Xiaolei Fan",

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year = "2021",

month = feb,

doi = "10.1016/j.micromeso.2020.110715",

language = "English",

volume = "311",

journal = "Microporous and Mesoporous Materials",

issn = "1387-1811",

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Abdulridha, S, Zhang, R, Xu, S, Tedstone, A, Ou, X, Gong, J, Mao, B, Frogley, M, Bawn, C, Zhou, Z, Zhang, X, Chansai, S, Holmes, SM, Hardacre, C, Garforth, AA, Yang, S, Jiao, Y & Fan, X 2021, 'An efficient microwave-assisted chelation (MWAC) post-synthetic modification method to produce hierarchical Y zeolites', Microporous and Mesoporous Materials, vol. 311, 110715. https://doi.org/10.1016/j.micromeso.2020.110715

TY - JOUR

T1 - An efficient microwave-assisted chelation (MWAC) post-synthetic modification method to produce hierarchical Y zeolites

AU - Abdulridha, Samer

AU - Zhang, Rongxin

AU - Xu, Shaojun

AU - Tedstone, Aleksander

AU - Ou, Xiaoxia

AU - Gong, Jiacheng

AU - Mao, Boyang

AU - Frogley, Mark

AU - Bawn, Carlo

AU - Zhou, Zhaoxia

AU - Zhang, Xinran

AU - Chansai, Sarayute

AU - Holmes, Stuart M.

AU - Hardacre, Christopher

AU - Garforth, Arthur A.

AU - Yang, Sihai

AU - Jiao, Yilai

AU - Fan, Xiaolei

PY - 2021/2

Y1 - 2021/2

N2 - We report a low-cost, highly energy efficient microwave-assisted chelation (MWAC) method, which enabled the post-synthetic modification of synthetic zeolites for adopting hierarchical structures within minutes. Exemplified by Zeolite Y, hierarchical Y zeolites prepared in this way showed exceptional specific external surface areas of >300 m2 g−1 and mesopore volumes of >0.46 cm3 g−1. Comparative assessments revealed that developed zeolites have shown significantly improved catalytic activities for catalysis involving large substrates, such as catalytic cracking and hydrocracking of plastics.

AB - We report a low-cost, highly energy efficient microwave-assisted chelation (MWAC) method, which enabled the post-synthetic modification of synthetic zeolites for adopting hierarchical structures within minutes. Exemplified by Zeolite Y, hierarchical Y zeolites prepared in this way showed exceptional specific external surface areas of >300 m2 g−1 and mesopore volumes of >0.46 cm3 g−1. Comparative assessments revealed that developed zeolites have shown significantly improved catalytic activities for catalysis involving large substrates, such as catalytic cracking and hydrocracking of plastics.

KW - Catalysis

KW - Hierarchical zeolites

KW - Microwave irradiation

KW - Post-synthetic treatment

UR - http://www.scopus.com/inward/record.url?scp=85093931128&partnerID=8YFLogxK

U2 - 10.1016/j.micromeso.2020.110715

DO - 10.1016/j.micromeso.2020.110715

M3 - Article

AN - SCOPUS:85093931128

SN - 1387-1811

VL - 311

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

M1 - 110715

ER -

An efficient microwave-assisted chelation (MWAC) post-synthetic modification method to produce hierarchical Y zeolites

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

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