Examining trends and variability of PM_2.5-associated organic and elemental carbon in the megacity of Beijing, China: Insight from decadal continuous in-situ hourly observations

Organic carbon (OC) and elemental carbon (EC) in fine particulate matter (PM_2.5) play pivotal roles in impacting human health, air quality, and climate change dynamics. Long-term monitoring datasets of OC and EC in PM_2.5 are indispensable for comprehending their temporal variations, spatial distribution, evolutionary patterns, and trends, as well as for assessing the effectiveness of clean air action plans. This study presents and scrutinizes a comprehensive 10-year hourly dataset of PM_2.5-bound OC and EC in the megacity of Beijing, China, spanning from 2013 to 2022. Throughout the entire study period, the average concentrations of OC and EC were recorded at 8.8 ± 8.7 and 2.5 ± 3.0 μg/m³, respectively. Employing the seasonal and trend decomposition methodology, specifically the locally estimated scatter plot smoothing method combined with generalized least squares with the autoregressive moving average method, the study observed a significant decline in OC and EC concentrations, reducing by 5.8 % yr⁻¹ and 9.9 % yr⁻¹ at rates of 0.8 and 0.4 μg/m³ yr⁻¹, respectively. These declining trends were consistently verified using Theil-Sen method. Notably, the winter months exhibited the most substantial declining trends, with rates of 9.3 % yr⁻¹ for OC and 10.9 % yr⁻¹ for EC, aligning with the positive impact of the implemented clean air action plan. Weekend spikes in OC and EC levels were attributed to factors such as traffic regulations and residential emissions. Diurnal variations showcased higher concentrations during nighttime and lower levels during daytime. Although meteorological factors demonstrated an overall positive impact with average reduction in OC and EC concentrations by 8.3 % and 8.7 %, clean air action plans including the Air Pollution Prevention and Control Action Plan (2013–2017) and the Three-Year Action Plan to Win the Blue Sky War (2018–2020) have more contributions in reducing the OC and EC concentrations with mass drop rates of 87.1 % and 89.2 % and 76.7 % and 96.7 %, respectively. Utilizing the non-parametric wind regression method, significant concentration hotspots were identified at wind speeds of ≤2 m/s, with diffuse signals recorded in the southwestern wind sectors at wind speeds of approximately 4–5 m/s. Interannual disparities in potential source regions of OC and EC were evident, with high potential source areas observed in the southern and northwestern provinces of Beijing from 2013 to 2018. In contrast, during 2019–2022, potential source areas with relatively high values of potential source contribution function were predominantly situated in the southern regions of Beijing. This analysis, grounded in observational data, provides insights into the decadal changes in the major atmospheric composition of PM_2.5 and facilitates the evaluation of the efficacy of control policies, particularly relevant for developing countries.