TY - JOUR
T1 - Green synthesis of Fe[sbnd]Ni[sbnd]Sn trimetallic oxides from Moringa oleifera for photocatalytic degradation of Reactive Red 6B dye
AU - Hassan, Fahad
AU - Batool, Iqra
AU - Nawaz, Rabia
AU - Ali, Omar Makram
AU - Almasoudi, Afaf
AU - Zidan, Ammar
AU - Baamer, Doaa F.
AU - Elahi, Muhammad Saqib
AU - Raheel, Ahmad
AU - Bahadur, Ali
AU - Taj, Muhammad Babar
AU - Iqbal, Shahid
AU - Rizwan, Komal
AU - Mahmood, Sajid
N1 - Publisher Copyright:
© 2024 Elsevier B.V.
PY - 2025/1/5
Y1 - 2025/1/5
N2 - The nanocomposite Fe[sbnd]Ni[sbnd]Sn trimetallic oxides were synthesized using an aqueous Moringa Oleifera leaf extract. The prepared nanocomposite was analyzed using SEM, FTIR, XRD, N2 adsorption-desorption, Zeta potential, and UV–vis analysis. A common Azo dye named Reactive Red 6B (RR-6B), widely applied in the dyeing industry and causing environmental pollution, was selected to examine the photodegradation of Fe[sbnd]Ni[sbnd]Sn trimetallic oxides nanocomposite under sunlight irradiation, and it was shown that this dye could be successfully degraded by prepared nanocomposite. Effects of parameters such as inorganic salt concentration, H2O2 concentration, contact time, pH, and impact of different concentrations of catalyst and dye were examined to find out degradation conditions. This prepared nanocomposite was applied for the photodegradation of RR-6B dye, and 95 % degradation efficiency was obtained at pH 4, 10 mg of catalyst concentration, 10 ppm of dye concentration, and contact time of 2 h. Degradation kinetics were carried out using Langmuir-Hinshelwood and first-order reaction models. These results showed a facile technique for forming nanocomposite to efficiently degrade organic contaminants from wastewater, which directly impacts industrial wastewater treatment. The antibacterial activity was performed using the Time assay kill method for Gram-positive S. aureus and Gram-negative E. coli bacteria. The results of antibacterial activity showed an inhibition effect on bacterial growth by trimetallic oxides NPs, suggesting their potential use in antimicrobial coatings and materials. These findings underscore the practical applications of our research, demonstrating its relevance and potential impact in real-world scenarios.
AB - The nanocomposite Fe[sbnd]Ni[sbnd]Sn trimetallic oxides were synthesized using an aqueous Moringa Oleifera leaf extract. The prepared nanocomposite was analyzed using SEM, FTIR, XRD, N2 adsorption-desorption, Zeta potential, and UV–vis analysis. A common Azo dye named Reactive Red 6B (RR-6B), widely applied in the dyeing industry and causing environmental pollution, was selected to examine the photodegradation of Fe[sbnd]Ni[sbnd]Sn trimetallic oxides nanocomposite under sunlight irradiation, and it was shown that this dye could be successfully degraded by prepared nanocomposite. Effects of parameters such as inorganic salt concentration, H2O2 concentration, contact time, pH, and impact of different concentrations of catalyst and dye were examined to find out degradation conditions. This prepared nanocomposite was applied for the photodegradation of RR-6B dye, and 95 % degradation efficiency was obtained at pH 4, 10 mg of catalyst concentration, 10 ppm of dye concentration, and contact time of 2 h. Degradation kinetics were carried out using Langmuir-Hinshelwood and first-order reaction models. These results showed a facile technique for forming nanocomposite to efficiently degrade organic contaminants from wastewater, which directly impacts industrial wastewater treatment. The antibacterial activity was performed using the Time assay kill method for Gram-positive S. aureus and Gram-negative E. coli bacteria. The results of antibacterial activity showed an inhibition effect on bacterial growth by trimetallic oxides NPs, suggesting their potential use in antimicrobial coatings and materials. These findings underscore the practical applications of our research, demonstrating its relevance and potential impact in real-world scenarios.
KW - Antibacterial activity
KW - Green synthesis
KW - Moringa oleifera
KW - Ni-Fe-Sn oxides
KW - Reactive Red 6B dye
UR - http://www.scopus.com/inward/record.url?scp=85200541363&partnerID=8YFLogxK
U2 - 10.1016/j.molstruc.2024.139546
DO - 10.1016/j.molstruc.2024.139546
M3 - Article
AN - SCOPUS:85200541363
SN - 0022-2860
VL - 1319
JO - Journal of Molecular Structure
JF - Journal of Molecular Structure
M1 - 139546
ER -