In-situ IR monitoring of the formation of Zr-fumarate MOF

Jianwei Ren; Nicholas M. Musyoka; Henrietta W. Langmi; Brian C. North; Mkhulu Mathe; Wan Pang; Mingjie Wang; Joseph Walker

doi:10.1016/j.apsusc.2017.01.271

In-situ IR monitoring of the formation of Zr-fumarate MOF

Jianwei Ren, Nicholas M. Musyoka, Henrietta W. Langmi, Brian C. North, Mkhulu Mathe, Wan Pang, Mingjie Wang, Joseph Walker

Research output: Journal Publication › Article › peer-review

26 Citations (Scopus)

Abstract

The in-situ IR technique was employed to monitor the crystallization process of Zr-fumarate (Zr-fum) MOF under real synthesis conditions. The results evidenced the participations of both modulator acid (HCOOH) and solvent (DMF) during the structural formation of Zr-fum MOF. This observation will contribute to the quest for understanding of the formation of structural defects in MOFs, which is a topic that is currently under intense investigation.

Original language	English
Pages (from-to)	263-267
Number of pages	5
Journal	Applied Surface Science
Volume	404
DOIs	https://doi.org/10.1016/j.apsusc.2017.01.271
Publication status	Published - 15 May 2017
Externally published	Yes

Keywords

IR spectroscopy
Metal-organic frameworks
NMR spectroscopy

ASJC Scopus subject areas

General Chemistry
Condensed Matter Physics
General Physics and Astronomy
Surfaces and Interfaces
Surfaces, Coatings and Films

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10.1016/j.apsusc.2017.01.271

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title = "In-situ IR monitoring of the formation of Zr-fumarate MOF",

abstract = "The in-situ IR technique was employed to monitor the crystallization process of Zr-fumarate (Zr-fum) MOF under real synthesis conditions. The results evidenced the participations of both modulator acid (HCOOH) and solvent (DMF) during the structural formation of Zr-fum MOF. This observation will contribute to the quest for understanding of the formation of structural defects in MOFs, which is a topic that is currently under intense investigation.",

keywords = "IR spectroscopy, Metal-organic frameworks, NMR spectroscopy",

author = "Jianwei Ren and Musyoka, {Nicholas M.} and Langmi, {Henrietta W.} and North, {Brian C.} and Mkhulu Mathe and Wan Pang and Mingjie Wang and Joseph Walker",

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year = "2017",

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doi = "10.1016/j.apsusc.2017.01.271",

language = "English",

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T1 - In-situ IR monitoring of the formation of Zr-fumarate MOF

AU - Ren, Jianwei

AU - Musyoka, Nicholas M.

AU - Langmi, Henrietta W.

AU - North, Brian C.

AU - Mathe, Mkhulu

AU - Pang, Wan

AU - Wang, Mingjie

AU - Walker, Joseph

PY - 2017/5/15

Y1 - 2017/5/15

N2 - The in-situ IR technique was employed to monitor the crystallization process of Zr-fumarate (Zr-fum) MOF under real synthesis conditions. The results evidenced the participations of both modulator acid (HCOOH) and solvent (DMF) during the structural formation of Zr-fum MOF. This observation will contribute to the quest for understanding of the formation of structural defects in MOFs, which is a topic that is currently under intense investigation.

AB - The in-situ IR technique was employed to monitor the crystallization process of Zr-fumarate (Zr-fum) MOF under real synthesis conditions. The results evidenced the participations of both modulator acid (HCOOH) and solvent (DMF) during the structural formation of Zr-fum MOF. This observation will contribute to the quest for understanding of the formation of structural defects in MOFs, which is a topic that is currently under intense investigation.

KW - IR spectroscopy

KW - Metal-organic frameworks

KW - NMR spectroscopy

UR - http://www.scopus.com/inward/record.url?scp=85011832379&partnerID=8YFLogxK

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DO - 10.1016/j.apsusc.2017.01.271

M3 - Article

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SN - 0169-4332

VL - 404

SP - 263

EP - 267

JO - Applied Surface Science

JF - Applied Surface Science

ER -

In-situ IR monitoring of the formation of Zr-fumarate MOF

Abstract

Keywords

ASJC Scopus subject areas

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