In Situ Sulfidation of Pd/C: A Straightforward Method for Chemoselective Conjugate Reduction by Continuous Hydrogenation

Jonathan C. Moore; Rowena A. Howie; Samuel L. Bourne; Gareth N. Jenkins; Peter Licence; Martyn Poliakoff; Michael W. George

doi:10.1021/acssuschemeng.9b04347

In Situ Sulfidation of Pd/C: A Straightforward Method for Chemoselective Conjugate Reduction by Continuous Hydrogenation

Jonathan C. Moore, Rowena A. Howie, Samuel L. Bourne, Gareth N. Jenkins, Peter Licence, Martyn Poliakoff, Michael W. George

Department of Chemical and Environmental Engineering

Research output: Journal Publication › Article › peer-review

6 Citations (Scopus)

Abstract

A method has been developed for the in situ sulfidation of Pd/C under continuous flow. The approach provides a cheap, sustainable, and operationally convenient method for chemoselective conjugate reduction by continuous hydrogenation. High conversions and excellent selectivities were obtained for olefin reduction in α/β-unsaturated carbonyl compounds in the presence of hydrogenatively sensitive functionalities. The methodology was analyzed with a green metric system to highlight the sustainability features of the process.

Original language	English
Pages (from-to)	16814-16819
Number of pages	6
Journal	ACS Sustainable Chemistry and Engineering
Volume	7
Issue number	19
DOIs	https://doi.org/10.1021/acssuschemeng.9b04347
Publication status	Published - 7 Oct 2019

ASJC Scopus subject areas

General Chemistry
Environmental Chemistry
General Chemical Engineering
Renewable Energy, Sustainability and the Environment

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10.1021/acssuschemeng.9b04347

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title = "In Situ Sulfidation of Pd/C: A Straightforward Method for Chemoselective Conjugate Reduction by Continuous Hydrogenation",

abstract = "A method has been developed for the in situ sulfidation of Pd/C under continuous flow. The approach provides a cheap, sustainable, and operationally convenient method for chemoselective conjugate reduction by continuous hydrogenation. High conversions and excellent selectivities were obtained for olefin reduction in α/β-unsaturated carbonyl compounds in the presence of hydrogenatively sensitive functionalities. The methodology was analyzed with a green metric system to highlight the sustainability features of the process.",

author = "Moore, {Jonathan C.} and Howie, {Rowena A.} and Bourne, {Samuel L.} and Jenkins, {Gareth N.} and Peter Licence and Martyn Poliakoff and George, {Michael W.}",

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T2 - A Straightforward Method for Chemoselective Conjugate Reduction by Continuous Hydrogenation

AU - Moore, Jonathan C.

AU - Howie, Rowena A.

AU - Bourne, Samuel L.

AU - Jenkins, Gareth N.

AU - Licence, Peter

AU - Poliakoff, Martyn

AU - George, Michael W.

PY - 2019/10/7

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N2 - A method has been developed for the in situ sulfidation of Pd/C under continuous flow. The approach provides a cheap, sustainable, and operationally convenient method for chemoselective conjugate reduction by continuous hydrogenation. High conversions and excellent selectivities were obtained for olefin reduction in α/β-unsaturated carbonyl compounds in the presence of hydrogenatively sensitive functionalities. The methodology was analyzed with a green metric system to highlight the sustainability features of the process.

AB - A method has been developed for the in situ sulfidation of Pd/C under continuous flow. The approach provides a cheap, sustainable, and operationally convenient method for chemoselective conjugate reduction by continuous hydrogenation. High conversions and excellent selectivities were obtained for olefin reduction in α/β-unsaturated carbonyl compounds in the presence of hydrogenatively sensitive functionalities. The methodology was analyzed with a green metric system to highlight the sustainability features of the process.

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IS - 19

ER -

In Situ Sulfidation of Pd/C: A Straightforward Method for Chemoselective Conjugate Reduction by Continuous Hydrogenation

Abstract

ASJC Scopus subject areas

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