Integration of Mn-ZnFe₂O₄ with S-g-C₃N₄ for Boosting Spatial Charge Generation and Separation as an Efficient Photocatalyst

The disposal of dyes and organic matter into water bodies has become a significant source of pollution, posing health risks to humans worldwide. With rising water demands and dwindling supplies, these harmful compounds must be isolated from wastewater and kept out of the aquatic environment. In the research presented here, hydrothermal synthesis of manganese-doped zinc ferrites’ (Mn-ZnFe₂O₄) nanoparticles (NPs) and their nanocomposites (NCs) with sulfur-doped graphitic carbon nitride (Mn-ZnFe₂O₄/S-g-C₃N₄) are described. The samples’ morphological, structural, and bonding features were investigated using SEM, XRD, and FTIR techniques. A two-phase photocatalytic degradation study of (0.5, 1, 3, 5, 7, 9, and 11 wt.%) Mn-doped ZnFe₂O₄ NPs and Mn-ZnFe₂O₄/(10, 30, 50, 60, and 70 wt.%) S-g-C₃N₄ NCs against MB was carried out to find the photocatalyst with maximum efficiency. The 9% Mn-ZnFe₂O₄ NPs and Mn-ZnFe₂O₄/50% S-g-C₃N₄ NCs exhibited the best photocatalyst efficiency in phase one and phased two, respectively. The enhanced photocatalytic activity of the Mn-ZnFe₂O₄/50% S-g-C₃N₄ NCs could be attributed to synergistic interactions at the Mn-ZnFe₂O₄/50% S-g-C₃N₄ NCs interface that resulted in a more effective transfer and separation of photo-induced charges. Therefore, it is efficient, affordable, and ecologically secure to modify ZnFe₂O₄ by doping with Mn and homogenizing with S-g-C₃N₄. As a result, our current research suggests that the synthetic ternary hybrid Mn-ZnFe₂O₄/50% S-g-C₃N₄ NCs may be an effective photocatalytic system for degrading organic pollutants from wastewater.