Redox mediation enabled by immobilised centres in the pores of a metal–organic framework grown by liquid phase epitaxy

André Dragässer; Osama Shekhah; Olexandra Zybaylo; Cai Shen; Manfred Buck; Christof Wöll; Derck Schlettwein

doi:10.1039/c1cc16580a

Redox mediation enabled by immobilised centres in the pores of a metal–organic framework grown by liquid phase epitaxy

André Dragässer, Osama Shekhah, Olexandra Zybaylo, Cai Shen, Manfred Buck, Christof Wöll, Derck Schlettwein

Research output: Journal Publication › Article › peer-review

89 Citations (Scopus)

Abstract

A layer of a metal–organic framework (SURMOF) was prepared on a thiol monolayer on Au. Charge transport across the insulating membrane could be established by using ferrocene as an immobilised redox mediator. Reversibility of the immobilisation and its role in the electrode kinetics are discussed.

Original language	English
Pages (from-to)	663-665
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	5
DOIs	https://doi.org/10.1039/c1cc16580a
Publication status	Published - 12 Dec 2012
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c1cc16580a

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abstract = "A layer of a metal–organic framework (SURMOF) was prepared on a thiol monolayer on Au. Charge transport across the insulating membrane could be established by using ferrocene as an immobilised redox mediator. Reversibility of the immobilisation and its role in the electrode kinetics are discussed.",

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AU - Dragässer, André

AU - Shekhah, Osama

AU - Zybaylo, Olexandra

AU - Shen, Cai

AU - Buck, Manfred

AU - Wöll, Christof

AU - Schlettwein, Derck

PY - 2012/12/12

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AB - A layer of a metal–organic framework (SURMOF) was prepared on a thiol monolayer on Au. Charge transport across the insulating membrane could be established by using ferrocene as an immobilised redox mediator. Reversibility of the immobilisation and its role in the electrode kinetics are discussed.

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JO - Chemical Communications

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IS - 5

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Redox mediation enabled by immobilised centres in the pores of a metal–organic framework grown by liquid phase epitaxy

Abstract

ASJC Scopus subject areas

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