Revolutionizing textile wastewater treatment: Enhanced degradation of dyes using bimetallic Zinc Ferrite-GO nanocomposites

Shagufta Rasheed, Sohail Nadeem, Rabia Nawaz, Shumaila Razzaque, Asif Mahmood, Ammar Zidan, Waheed Al-Masry, Mohsin Javed, Nafeesa Allah Ditta, Ali Bahadur, Shahid Iqbal, Sajid Mahmood, Toheed Akhter

Research output: Journal PublicationArticlepeer-review

Abstract

A novel bimetallic nickel-copper doped zinc ferrite based catalyst has been synthesized using the hydrothermal method. The nano-sized bimetallic (Ni-Cu) zinc ferrites were embedded with graphene oxide (GO). The characterization of nano-sized bimetallic (Ni-Cu) zinc ferrites with graphene oxide (GO) involves a comprehensive set of analytical techniques to determine their elemental composition, structural properties, and morphological features. The prepared materials were also subjected to structural and morphological evaluation through FTIR, Raman, XRD, TGA, UV–vis spectroscopy, and SEM with EDX. The experiment for the photodegradation of the selected model pollutant dye, methylene blue was conducted using the prepared materials. This means that the present photocatalyst has a high efficiency of degrading the pollutant to a tune of 99 % within 3 h. When the amount of GO in the prepared nanocomposite was 40 %, there was the perfect result in terms of no degradation of MB. It reduced and deteriorated the degree of band gap energy of the MB dye. The photocatalyst activity was proven to be repeatable; the sample's use was again possible. A decrease in the band gap energy implies that the improved photocatalyst material becomes more efficient at absorbing light energy. This enhanced light absorption promotes the generation of electron-hole pairs, which are essential for catalytic reactions. Therefore, the reduction in band gap energy likely contributes to the catalyst's heightened ability to initiate the degradation of the MB dye, ultimately leading to more effective pollutant removal. In the future, the synthesized sample can be reused without significant loss in its catalytic efficiency, underscoring the stability and durability of the material. The current study has paramount importance for real-world applications; reliable performance over multiple cycles ensures that the catalyst remains effective in addressing pollution challenges over prolonged periods.

Original languageEnglish
Article number139480
JournalJournal of Molecular Structure
Volume1320
DOIs
Publication statusPublished - 15 Jan 2025

Keywords

  • GO nanocomposites
  • Hydrothermal method
  • MB dye degradation
  • Photocatalytic activity
  • physical characterizations

ASJC Scopus subject areas

  • Analytical Chemistry
  • Spectroscopy
  • Organic Chemistry
  • Inorganic Chemistry

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