TY - JOUR
T1 - Synergistic Influences of Doping Techniques and Well-Defined Heterointerface Formation to Improve the Photocatalytic Ability of the S-ZnO/GO Nanocomposite
AU - Javed, Mohsin
AU - Qamar, Muhammad Azam
AU - Iqbal, Shahid
AU - Aljazzar, Samar O.
AU - Iqbal, Sadia
AU - Khan, Humaira
AU - Abourehab, Mohammed A.S.
AU - Elkaeed, Eslam B.
AU - Alharthi, Abdulrahman I.
AU - Awwad, Nasser S.
AU - Ibrahium, Hala A.
N1 - Publisher Copyright:
© 2022 Wiley-VCH GmbH.
PY - 2022/8/5
Y1 - 2022/8/5
N2 - Environmental pollutants such as organic dyes are major focal areas of the current era. For this reason, excellent photocatalytic substances are needed time to degrade such water bodies and get pollution-free water. In this study, Sulphur doped zinc oxide nanoparticles were fabricated utilizing a solution-free technique, while graphene oxide was synthesized using a modified hummer‘s method. Sulphur-doped zinc oxide nanoparticles were mixed with graphene oxide in five distinct weight percentages to achieve the S-ZnO/GO (SZO) composites. The 8 % SZO NC demonstrated superior photocatalytic efficiency, degrading 100 % of MB in 110 minutes under sunlight irradiation. The synthesized composites were characterized by the techniques viz. TEM, SEM, EDXS, FTIR, XPS, and UV spectrophotometry to determine their chemical nature and morphological features. Methylene blue was used as a reference pollutant to evaluate the photocatalytic activity of the composites. According to the radical scavenger‘s test observations, •OH and •O2– were the primary species responsible for MB decomposition. Furthermore, the nanocomposites were found highly stable, with a continuously high degree of dye degradation throughout six catalytic cycles. As a result, the SZO nanocomposites have the prospective to be an extremely effective and versatile photocatalyst for the photodegradation of organic wastes.
AB - Environmental pollutants such as organic dyes are major focal areas of the current era. For this reason, excellent photocatalytic substances are needed time to degrade such water bodies and get pollution-free water. In this study, Sulphur doped zinc oxide nanoparticles were fabricated utilizing a solution-free technique, while graphene oxide was synthesized using a modified hummer‘s method. Sulphur-doped zinc oxide nanoparticles were mixed with graphene oxide in five distinct weight percentages to achieve the S-ZnO/GO (SZO) composites. The 8 % SZO NC demonstrated superior photocatalytic efficiency, degrading 100 % of MB in 110 minutes under sunlight irradiation. The synthesized composites were characterized by the techniques viz. TEM, SEM, EDXS, FTIR, XPS, and UV spectrophotometry to determine their chemical nature and morphological features. Methylene blue was used as a reference pollutant to evaluate the photocatalytic activity of the composites. According to the radical scavenger‘s test observations, •OH and •O2– were the primary species responsible for MB decomposition. Furthermore, the nanocomposites were found highly stable, with a continuously high degree of dye degradation throughout six catalytic cycles. As a result, the SZO nanocomposites have the prospective to be an extremely effective and versatile photocatalyst for the photodegradation of organic wastes.
KW - SZO nanocomposites
KW - active species
KW - heterointerface
KW - organic waste
KW - sunlight photocatalysis
UR - http://www.scopus.com/inward/record.url?scp=85135617130&partnerID=8YFLogxK
U2 - 10.1002/slct.202201913
DO - 10.1002/slct.202201913
M3 - Article
AN - SCOPUS:85135617130
SN - 2365-6549
VL - 7
JO - ChemistrySelect
JF - ChemistrySelect
IS - 29
M1 - e202201913
ER -